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Preheat oven to 180°C.
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Grate the zest and juice the orange.
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Place butter and half of the orange zest in a cast iron skillet (or any pan that goes in the oven); oven until almost completely melted. Remove 1,5 spoons of the melted butter and set aside. Return skillet to the oven.
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Mix together flour, sugar, a pinch of salt, milk, eggs, half of the orange juice, 1 teaspoon of cinnamon and 1 tablespoon of Countreau. Whisk, add the tablespoon of butter and whisk again.
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Remove the skillet from the oven (it should be very hot know, check that oven has reached the temperature again) and carefully pour the batter into it.
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Bake in the oven for 15- 20 minutes (you will see edges brown and the center puff).
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Meantime baine-marie honey, 1/2 teaspoon of cinnamon, the other half of the orange juice and zest and the other tablespoon of Countreau. Stir occasionally, until creamy (5-10 minutes).
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Remove the skillet from the oven and serve it hot with the honey syrup.